Not something I'd try on my own pride and joy: you might find that it doesn't run that well (confused oxygen sensor / engine management), may not pass an MoT (noise and / or emission levels), Mr Plod may take a dim view of it, and insurance would probably need to know (modification).
The other point is manufacturers spend £m on the R&D of these things to achieve a balance between function, cost, type approval, manufacturability and various other factors. Their engineers have access to a wealth of data incomprehensible to you and I, have umpteen years experience designing these systems and getting them to work, and in my view the average home mechanic is unlikely to improve on these things.